Lithium chloride is also used as a flame colorant to produce dark red flames. words matched: chloride, Lithium SRA028 – Rainbow flames Alcohol is added to a series of beakers or crystallizing dishes containing metal salts and boric acid. The salt is a typical ionic compound (with certain covalent characters) , although the small size of the Li ion gives rise to properties not seen for other alkali metal chlorides, such as extraordinary solubility in polar solvents (83.05 g/100 mL of water at 20 °C) and its hygroscopic properties. Boron trifluoride reacts with incandescence when heated with lithium [Merck 11th ed. Irritating to eyes and skin. [12], Lithium salts affect the central nervous system in a variety of ways. Jr,XH�Q��ƻ/�W�JJ���]�p��="�'�����!�jl��x��tI�G����.�E����EN�>�+J�;P�YF�T��|$��{()F%����{E���[ Y �f{BC�@تݯ5��jG�i��="�! May cause headache, muscle weakness and incoordination, and confusion. MSDS-0002 Rev. (lithium, sulfuryl chloride, thionyl chloride, chlorine) are considered hazardous under US OSHA and are subject to the requirements of 29 CFR 1200 Hazard Communication. (j) aspiration hazard Lithium chloride, a solid, does not present an aspiration hazard. Lithium chloride has been extensively tested for REACH registration Acute Effects From Overexposure: No data available for the formulation. : 7447-41-8 Molecular Weight: 42.39 Chemical Formula: LiCl Product Codes: J.T. (lithium, thionyl chloride) are considered hazardous under US OSHA and are subject to the requirements of 29 CFR 1200 Hazard Communication.. Lithium Battery Safety With proper use and handling, lithium batteries have demonstrated an excellent safety record. LITHIUM CHLORIDE . "� �����6¿^=��}d �5A��h�{�sW��a� �?Mo4%BH�ף](O7�"B��»c�B�`L1�6� Haz. CAS#: 7447-41-8. safety hazards of Copper Chloride to potentially exposed workers. Section 1: Chemical Product and Company Identification. ��Ʉ��[H8���s\�����`���E$Y�}u1��_ %PDF-1.6 %���� D ECO #11598 P a g e 1 Material Safety Data Sheet Product Name: LITHIUM THIONYL CHLORIDE CELLS AND BATTERIES Hermetically-Sealed Lithium Thionyl Chloride Cells & Batteries All Electrochem 100, 150, 150/165MR, 180/180MR, 200/200MR series, QTC, MWD, VHT Cells and Batteries h�bbd```b``��5 ��4�d���E4�lq�x-�d���K"�w�$7����3��$S�U��)�,`��1`��`���Ge �"� �#������:@� �� endstream endobj startxref 0 %%EOF 467 0 obj <>stream Severe deep burns. 1. Lithium chloride is mainly used for the production of lithium metal by electrolysis of a LiCl/KCl melt at 450 °C (842 °F). HUMAN EXPOSURE AND TOXICITY: Acute poisoning in man reported after 4 doses of 2 g each of lithium chloride, causing weakness, prostration, vertigo, and tinnitus. Causes redness and pain. LiCl is also used as a brazing flux for aluminium in automobile parts. Material Safety Data Sheet Lithium Chloride sc-203110 Hazard Alert Code Key: EXTREME HIGH MODERATE LOW Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME Lithium Chloride STATEMENT OF HAZARDOUS NATURE CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200. Series C-71. Lithium Battery Safety With proper use and handling, lithium batteries have demonstrated an excellent safety record. Many reactions may cause fire or explosion. Lithium chloride is a chemical compound with the formula LiCl. Explosion: Risk of fire and explosion on contact with combustible substances and water. h��X�n7�}Iи���|�IZ�n]���om�dHJ�}�pW�ʖ��b䡅�"��f�̜��$��� m�De^y�Qx�5R()�a�P�T�P6B��H:T�P��`�ˡB/�,2Ahmx�(���R�@U�H^�ja��a��+Y�� Skin: Redness. H�̗Mk�@�����jG�o9d������B���/�@Ӕ���^���M֘���k�<3�����,N��������ԕ���F�ÇWu%����G1z�����Hp]W�����`�1uW.t�1M�i�[�� c��14��1]��ki;K�A~��Ur��L��vZ�s�=�P>�m :�YWA���at. NACRES NA.23 Lithium chloride SDS Safety Data Sheet for Lithium chloride 105679. T n��ë��>T�u#����NF���0�L����ɷ�����&��0$�ޓ�������J���M]�y������t8xu8]����"rѮ+eմ��F��S�[}|k6�m�ټ������n�2�w:��'���� ���~�Z���W�&������6�����^���NA嘃`f=.�T�j�6� *�X��`=� Ingestion: Abdominal cramps. Lithium chloride 7447-41-8X -231-212-3X X XXKE-22552 U.S. Federal Regulations SARA 313 Not applicable SARA 311/312 Hazard CategoriesSee section 2 for more information CWA (Clean Water Act) Not applicable Clean Air Act Not applicable OSHA - Occupational Safety and Health Administration Not applicable CERCLA Not applicable PubChem Substance ID 24852187. NFPA SUPPLIER Santa Cruz Biotechnology, … Lithium chloride powder, ≥99.98% trace metals basis CAS Number 7447-41-8. No envisaged effects other than acute effects from local irritation lithium chloride. Dehydration, weight loss, slurred speech, blurred vision, sensory loss, ataxia (failure of muscular coordination), tremors, and convulsions may occur. 7447-41-8 Lithium chloride min 99% 231-212-3 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Harmful in contact with skin and if swallowed. ACUTE/CHRONIC HAZARDS: This compound is a mild irritant. While the citrate, carbonate, and orotate salts are currently used to treat bipolar disorder, other lithium salts including the chloride were used in the past. F3��-�5�"���:܂���.u�N�m� '0R l�;� �ü�,���8�8�:��H�} 1956]. Material Safety Data Sheet or SDS for Lithium chloride 105679 from Merck for download or viewing in the browser. The equilibrium LiCl concentration in the resulting solution is directly related to the relative humidity of the air. Large doses of lithium may cause dizziness, prostration, and kidney damage. Fires may be fought but only from safe fire fighting distance, evacuate all persons from immediate area of fire. The electrolyte is mainly solution of Lithium chloride (LiCl), and aluminum chloride (AlCl 3) in Thionyl chloride (SOCl 2). �%��U��M�y�!K�^��5�¼�AOe��Süupk�w�Ƽ{"�Y��w�߷�浫���S/����J Lithium Thionyl Chloride Battery Safety Data Sheet 3 May 2017 EN (English) 5/7 Aspiration hazard : Not classified Symptoms/effects after inhalation : Not expected to present a significant inhalation hazard under anticipated conditions of normal use. Lithium chloride is a chemical compound with the formula LiCl. Lithium Coupon. ��u�u��f5kx��ތ�L.���b8>φ����t6?�Lnso& ��w��" Chronic toxicity symptoms following ingestion of nonlethal doses of lithium chloride with … The percent relative humidity at 25 °C (77 °F) can be estimated, with minimal error in the range 10–30 °C (50–86 °F), from the following first order equation: RH=107.93-2.11C, where C is solution LiCl concentration, percent by mass. Flush eyes with running water for at least 15 minutes, keeping eyelids open. It is used as a desiccant for drying air streams. Material Safety Data Sheet Lithium chloride MSDS Section 1: Chemical Product and Company Identification Product Name: Lithium chloride Catalog Codes: SLL1366 CAS#: 7447-41-8 RTECS: OJ5950000 TSCA: TSCA 8(b) inventory: Lithium chloride CI#: Not available. The electrolyte is mainly solution of Lithium chloride (LiCl), and aluminum chloride (AlCl 3) in Thionyl chloride (SOCl 2). In developing Xenopus embryos, lithium chloride is observed to exert inhibition of GSK-3β (glycogen synthase kinase-3β), yet not reported to be a general inhibitor of other protein kinases. Linear Formula LiCl . 1962, Chem. 6: … The salt forms crystalline hydrates, unlike the other alkali metal chlorides. >V��DUg_?�ٴ�ӯu����Uq�Y ���-�:���X���%�u8�{Y}�����������s��ގ�vfY��o ���MB͊���Z� �uH�Ь�J?�/���mP8��1���4gR:͙�L��(Mj���P�s�lO��h5�枠8:=>���N��&%��+��|������Zxku|��M>FH,c`�X�`��. Additionally, lithium chloride can itself be used as a hygrometer. ;(Q�c+�Z�JY��V���'"�7�XJ˵��p���d~��Mt�R~���ˈY�Z>���&o�ә�9j8|��k8|��إ�s.�lw��;��h}4ҳ�Y���L`��1��ʧ��gm�_6��g����٢C�l=���8yv� ���d��%��S?�+�#�,�3�2���=JLi��w! Inhalation: Burning sensation. As with any other ionic chloride, solutions of lithium chloride can serve as a source of chloride ion, e.g., forming a precipitate upon treatment with silver nitrate: Lithium chloride is produced by treatment of lithium carbonate with hydrochloric acid. Effects of exposure to Lithium: Fire: Flammable. MDL number MFCD00011078. 402 0 obj <> endobj 424 0 obj <>/Filter/FlateDecode/ID[<75F8B29C5E5C094E8E8A203404A1AD96>]/Index[402 66]/Info 401 0 R/Length 109/Prev 456671/Root 403 0 R/Size 468/Type/XRef/W[1 3 1]>>stream Gives off irritating or toxic fumes (or gases) in a fire. Cough. Maleic anhydride decomposes explosively in the presence of lithium [Chemical Safety Data Sheet SD-88. 5.4 Further information No data available. May … At 25 °C (77 °F) a saturated solution (45.8%) of the salt will yield an equilibrium relative humidity of 11.30%. SUPPLEMENTARY SAFETY AND HEALTH DATA: If the battery is broken or leaked the main hazard is the electrolyte. Re: Lithium Chloride safety and alternatives CausticSymmetry on Sat Nov 14, 2015 11:23 am Pumbaa - My own success was based on internal use only, so my experience is … [7] The anhydrous salt can be regenerated by heating the hydrates. [11], Lithium chloride has been shown to have strong acaricidal properties, being effective against Varroa destructor in populations of honey bees. Info. Shortness of breath. ��c��}��M�(�Ohv�-ʿ (�s� endstream endobj 406 0 obj <>stream N… [5] Anhydrous LiCl is prepared from the hydrate by heating with a stream of hydrogen chloride. [�� ����x����2L��?���j7�Ea�Px���Y�sE�GՖ6�`9b��������+��$x�i�+�{��W*n˕����b��u�R��eXKV�m��@ �S��{�U Product Identification Synonyms: Lithium monochloride CAS No. Ey… It is not toxic by ingestion, but by its corrosive nature can be irritating to the skin and eyes, it can also irritate the nostrils (National Institute for Occupational Safety and Health, 2015). }�,@����)�����H �` E0� endstream endobj 403 0 obj <>/Metadata 16 0 R/Pages 400 0 R/StructTreeRoot 22 0 R/Type/Catalog>> endobj 404 0 obj <>/MediaBox[0 0 630 810]/Parent 400 0 R/Resources<>/ProcSet[/PDF/Text/ImageB/ImageC/ImageI]/XObject<>>>/Rotate 0/StructParents 0/Tabs/S/Type/Page>> endobj 405 0 obj <>stream Burning sensation. EC Number 231-212-3. In case of contact with eyes, check for wearing contact lenses and remove them immediately. Duration of exposure, concentration of the substance The salt is a typical ionic compound (with certain covalent characters) , although the small size of the Li+ ion gives rise to properties not seen for other alkali metal chlorides, such as extraordinary solubility in polar solvents (83.05 g/100 mL of water at 20 °C) and its hygroscopic properties.[5]. ��0�����X�D��Ai��G���ʄQ�fW��v[N�DN1���@� -L����>��anl®i�1S��{�䆬�2�Vo +�#��R\&�KᙱD��Kv ��6,m��@�[��6�Lp�!��"� ix�:�r�m1���rվ�h�yM���b�U'Cɮy]4���g�P���R�N�:�Գ���X���O���x�E)���� Sore throat. 1:380. 5.4 Further information No data available SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Lithium chloride, anhydrous Revision Date 18-Jan-2018 Autoignition Temperature Explosion Limits Upper No data available Lower No data available Sensitivity to Mechanical ImpactNo information available Sensitivity to Static DischargeNo information available Specific Hazards Arising … eCl@ss 38050203 . Laboured breathing. Lithium Chloride is an antiviral metal halide utilized in a variety of assays to study cell-fate and neurobiology. One instance of reversible noticeable hepatotoxicity has been reported. Skin burns. It is used as a dessicant. SUPPLEMENTARY SAFETY AND HEALTH DATA: If the battery is broken or leaked the main hazard is the electrolyte. h�b```�m���� ��ea��� �pP\������� 8��������6JF��ƈ����! Lithium chloride lbs lbs lbs SARA Hazard Categories: Acute Chronic Flammability Pressure Reactivity Lithium chloride Clean Air Act Categories: SOCMI HAP Volatile HAP Organic HAP Ozone Depleting Lithium chloride The information presented above is offered for informational purposes only. Ph Eur - Find MSDS or SDS, a COA, data sheets and more information. Material Safety Data Sheet Lithium chloride MSDS Section 1: Chemical Product and Company Identification Product Name: Lithium chloride Catalog Codes: SLL1366 CAS#: 7447-41-8 RTECS: OJ5950000 TSCA: TSCA 8(b) inventory: Lithium chloride CI#: Not available. Cold water can be used. Pain. LEAKING FLUID IS CORROSIVE. Eyes: Redness. Pain. Chlorine vapors and lithium react producing a luminous flame [Mellor 2, Supp. Abdominal pain. For a short time in the 1940s lithium chloride was manufactured as a salt substitute, but this was prohibited after the toxic effects of the compound (tremors, fatigue, nausea) were recognized. COPPER CHLORIDE page 2 of 6 This Fact Sheet is a summary source of information of all potential and most severe health hazards that may result from exposure. 3 Effective date : 10.24.2014 Page 2 of 7 Lithium Chloride, Reagent Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com Molecular Weight 42.39 . Also, in biochemical applications, it can be used to precipitate RNA from cellular extracts.[8]. Lithium chloride CAS 7447-41-8 for analysis EMSURE® ACS,Reag. Product Name: Lithium chloride. Section 3: Hazards Identification. LiCl also absorbs up to four equivalents of ammonia/mol. Fires may be fought but only from safe fire fighting distance, evacuate all persons from immediate area of fire. eψa������5���s_��؟nڂK��YG�@�1���(c���)�%�r�7�ޤ����'��lJC��X 5�? Treatment with Pamelor could be resumed 24 hours after the last dose of linezolid or intravenous methylene blue (see WARNINGS). Molten LiCl is used for the preparation of carbon nanotubes,[9] graphene[10] and lithium niobate. Potential Health Effect Eye: Causes moderate eye irritation. Lithium (Li) OSHA PEL N/A ACGIH TLV Not established Thionyl Chloride Aluminum Chloride (AlCl3) 1.0 ppm (4.9 3mg/m ) 2 3mg/m 1.0 ppm (4.9 3mg/m ) 2 mg/m3 Lithium Chloride Not established Not established SECTION 3 - Hazards Identification **DANGER** INTERNAL CONTENTS ARE EXTREMELY HAZARDOUS. 6bd�H�@1�:� Cc7�����s�L�s�4���{�iWzm�} )���� �y�. 1960]. Blisters. Symptoms may be delayed. [13][14][15], Except where otherwise noted, data are given for materials in their, ChemIDplus - 7447-41-8 - KWGKDLIKAYFUFQ-UHFFFAOYSA-M - Lithium chloride - Similar structures search, synonyms, formulas, resource links, and other chemical information, Ullmann's Encyclopedia of Industrial Chemistry, "Large-scale preparation of graphene by high temperature insertion of hydrogen into graphite", "Lithium chloride effectively kills the honey bee parasite, https://en.wikipedia.org/w/index.php?title=Lithium_chloride&oldid=996316359, Chemical articles with multiple compound IDs, Multiple chemicals in an infobox that need indexing, Pages using collapsible list with both background and text-align in titlestyle, Articles containing unverified chemical infoboxes, Creative Commons Attribution-ShareAlike License, R. Vatassery, titration analysis of LiCl, sat'd in Ethanol by AgNO, This page was last edited on 25 December 2020, at 21:15. This deliquescent salt forms a self-solution when exposed to air. 5.2 Special hazards arising from the substance or mixture Hydrogen chloride gas, Lithium oxides Hydrogen chloride gas, Lithium oxides 5.3 Advice for firefighters Wear self-contained breathing apparatus for firefighting if necessary. Lithium Chloride No exposure limit established No exposure limit established Appropriate Engineering Controls : Whenever possible the use of local exhaust ventilation or other engineering controls is the preferred method of controlling exposure to airborne dust … �('��X˘��P���� �C�T�� ��8w+���xq|.�2��"��#c�(HZ���G�S�|��N*�;� Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. New Reagents for Selective Metalation, Deprotonation, and 1,2-Additions. Lithium chloride is used as a relative humidity standard in the calibration of hygrometers. Health Hazard SYMPTOMS: Symptoms of exposure to this compound may include vomiting, profuse diarrhea, ataxia, coma, convulsions and local irritation of the skin, eyes and mucous membranes. If a battery ruptures, may be … [5] In more specialized applications, lithium chloride finds some use in organic synthesis, e.g., as an additive in the Stille reaction. 5.2 Special hazards arising from the substance or mixture Hydrogen chloride gas, Lithium oxides 5.3 Advice for firefighters Wear self-contained breathing apparatus for firefighting if necessary. Lithium chloride is a stable compound incompatible with strong oxidizing agents, strong acids, bromine trichloride, bromine trifluoride. 1989]. [6] Mono-, tri-, and pentahydrates are known. Mellor 2, Supp �r�7�ޤ����'��lJC��X 5� [ 9 ] graphene [ 10 and! With proper use and handling, lithium batteries have demonstrated an excellent Safety.! Use and handling, lithium salts affect the central nervous system in a variety of assays to cell-fate... 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